Atomic Number: 30
Symbol: Zn
Atomic Weight: 65.38
Electron Configuration: (Ar)4s23d10
Isotopes: There are 21 known isotopes, 5 stable and 16 unstable
Melting Point: 419.58° C
Boiling Point: 907° C
Specific Gravity: 7.133 @ STP
Valence: 2
Typical Physical Characteristics of Our Zinc Products
Flake Sizes available:
Z45:10- 44 um (Z45 Aspect Ratio: 30um x 10um average)
Z125: 45-125um
Z425: 125-425um
Z600:
425-600um
Tap Density: 1.8-2.3 cm3/g
Flake Thickness: 1-2 um average
Total Zinc %minimum: 99
Metallic Zinc % minimum: 97
Iron % maximum: 0.002
Lead % maximum: 0.002
Copper % maximum: 0.001
Cadmium % maximum: 0.001
Zinc Oxide: Balance
MSDS (pdf)
Product
Information Sheet (pdf)
APPLICATIONS
Dip Spin coatings - Government regulations and product
performance requirements are causing plating processes to be
converted to coating processes. These regulations have
practically eliminated the use of chrome, lead and other
elements which are unfriendly to the environment.
Additionally,
component and fastener manufacturers must adhere to more
stringent specifications which provide better salt spray
performance and more consistent torque tension capabilities.
Due to the fact that fasteners must maintain their manufactured
tolerances, galvanization, plating nor dust based protection can
be used because those processes distort the integrity of the
part. Only a zinc flake based coating allows the corrosion
protection necessary while at the same time preserving the part
characteristics.
In
this process parts are placed on a conveyor and then metered by
weight into a wire mesh basket. The basket is submerged into a
coating vat. The basket is then raised out of the zinc flake
based coating solution and then spun at up to 600 rpm while
still in the vat. The excess coating that is spun off drain back
into the vat for reuse.
Some systems allow for the basket to be tilted and/or vibrated
in order to eliminate “kiss marks” and to ensure even
distribution of the protective coating. Depending upon the
application, the coating viscosity, temperature, spin velocity
and curing time can be varied to achieve desired coating
thickness and consistent repeatability.
Zinc-rich Paints – These coatings have long been
recognized for their excellent adherence to both new and
weathered surfaces. Zinc-rich paints have
been
used for more than a century. One of the key reasons for the
success of zinc-rich paints is their combination of barrier and
cathodic protection.
In
a 1960’s study by the American Iron and Steel Structures
Painting Council, zinc-rich paints outperformed all other
classes of paint. Significantly, at the nine-year inspection in
1970, there was no loss of adhesion to the substrate.
Zinc-rich paints possess similar characteristics to a hot-dip
galvanized surface coating. Recent studies at the University of
Pennsylvania and University of Wales Swansea
http://www.swan.ac.uk/mateng/corrosion/NeilEurocorr.pdf have
shown that flaked zinc in combination with traditional spherical
dust provide equal or better corrosion protection with a lower
zinc loading percentage.
With metal prices at record levels, a lower loading percentage
can mean significant cost savings in the manufacturing of these
coatings. Additionally, the morphology of the flake provides a
superior cathodic connection in the dried coating due to the
overlapping nature of the lamellar particle. Zinc-rich paints
are also an approved method for the repair of damaged galvanized
coatings according to ASTM A 780.
Zinc/Air Batteries - also called zinc/air fuel cells are
a non-rechargeable electro-chemical battery, powered by the
oxidation of zinc with oxygen from the air. These batteries have
very high energy densities and are relatively inexpensive to
produce.
These
batteries are used in hearing aids, small electronics and in
experimental electric vehicles. Particles of zinc are mixed with
an electrolyte, such as potassium hydroxide, to make the gelled
or paste anode.
Water and oxygen from the air act as a cathode and form
hydroxyls which migrate into the zinc anode and form zincate,
Zn(OH)42- at which point electrons are released that travel back
to the cathode. The zincate decays into zinc oxide and water and
is released back into the system.
The water and hydroxyls from the anode are recycled at the
cathode. These reactions produce voltage levels near a max of
1.65 v.
The morphology of the zinc used is critical to the power density
of the battery. A spherical dust does not work as well as a zinc
particle that has a high aspect ratio. Zinc flake has a
morphology that allows a shapeable gel while at the same time
maximizing the amount of zinc available as an anode without
increasing the amount used. The end result is a more powerful
battery that costs less to manufacture.